d(ln(kH))/d(1/T) = Temperature dependence constant (K), Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes, Data compiled as indicated in comments: A method for forming a multilayer meltblown composite, consisting of: meltblowing a first material to form a first meltblown layer, wherein the first material comprises one or more resins having an Ultimate Elongation (UE) of from about 50% to about 250%; meltblowing a second material to form a second meltblown layer, wherein the second material comprises one or more . Weight of Evidence for Cancer (PDF) (14 pp, 118 K) Rohc, Vladislav; Ruzicka, Vlastimil; Ruzicka, Kvetoslav; Polednicek, Milos; Aim, Karel; Jose, Jacques; Zbransk, Milan, Requires a JavaScript / HTML 5 canvas capable browser. Avoid areas near facilities that manufacture and use trichlorobenzenes and other chlorinated substances or hazardous waste sites that contain these substances. Journal of Chromatography A, 1994, 672, 1-2, 141-148, https://doi.org/10.1016/0021-9673(94)80602-0 Shanghai Jizhi Biochemical Technology Co., Ltd, 1,2,4-Trichlorobenzene suppliers in China, 5-(4-Chlorophenoxy)-1,2,4-trichlorobenzene, 5-((4-Chlorophenyl)sulfinyl)-1,2,4-trichlorobenzene, 1,2,4-tris(methylthio)-3,5,6-trichlorobenzene. How can families reduce their risk for exposure to trichlorobenzenes? Thermochim. Advanced; SDS; Certificates; Chemical Structure Animal studies have shown that 1,2,4-trichlorobenzene affects the liver and kidney, and is possibly a teratogen. . Product Classification | Maintain clean baselines and improve chromatography run reproducibility with efficient filtration. P264: Wash skin thoroughly after handling. [all data], Rohc, Ruzicka, et al., 1998 Structure, properties, spectra, suppliers and links for: 1,1'-[(4-{2-[4-(Dimethyliminio)-2,5-cyclohexadien-1-ylidene]ethylidene}-4H-pyran-2,6-diyl)di-2,1. The standard enthalpies of formation of mono-1,2,4- and 1,3,5-tri-, and 1,2,3,4- and 1,2,3,5-tetrachlorobenzenes, Eur. Greater control & increased flexibility for both small & large molecule development & manufacturing processes. Physical Properties. Physical Properties of Chemical Compounds, Advances in Chemistry Series No. [all data], Petit and TerMinassian, 1974 J. Phys. Incompatible with strong oxidizing agents. It is virtually the exclusive product from the chlorination of 1,4-dichlorobenzene. The Preparation of 2,3,5-Trichlorophenoxyacetic acid (2,4,5-T), ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein, log10(P) = A (B / (T + C)) Your fast track through regulatory challenges.. Functional excipients to enhance bioavailability. Articles of 1,2,4-Trichlorobenzene are included as well. its accompanying search program. Trichlorobenzenes have primarily been used as solvents and chemical intermediates to produce other compounds. Converge, Intensify and Evolve. Contents 1 Production and uses 2 Safety 3 See also 4 References Production and uses [ edit] H unsym-trichlorobenzene; 1,2,4-trichlorobenzol. [ 1] Application 1,2,4-Trichlorobenzene may be used as a solvent to prepare: dimethylketene -lactone dimer from tetramethyl-1,3-cyclobutanedione [ 2] Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. other in their chemical structure. Properties Grade anhydrous 1,2,4-Trichlorobenzene 98.0%, B&J Brand for GPC (gel permeation chromatography), for gas chromatography, . Cookies used to make website functionality more relevant to you. Please see the following for information about Trichlorobenzenes have been detected in groundwater, drinking water, and surface water (rivers and lakes). Chem. * 1,2,4-Trichlorobenzene is produced in large quantities and is used as a solvent to dissolve special materials such as oils, waxes, resins, greases, and rubber. The LD50 (oral, rats) is 756mg/kg. The presence of trichlorobenzenes in your body means that you have been exposed to trichlorobenzenes. Optimize your QC lab workflow and ensure regulatory compliance. There are no studies of cancer in people exposed to trichlorobenzenes. Trichlorobenzenes have been used as solvents. Wilhelm, E.; Inglese, A.; Quint, J.R.; Grolier, J.-P.E., It is a derivative of benzene with three chloride substituents. jcamp-dx.js and Copyright for NIST Standard Reference Data is governed by [1] Trichlorobenzenes are man-made chemical compounds that occur in three different forms. It's important you understand this information because this substance may harm you. LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi, Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes, Data compiled by: Tanya L. Myers, Russell G. Tonkyn, Ashley M. Oeck, Tyler O. Danby, John S. Loring, Matthew S. Taubman, Stephen W. Sharpe, Jerome C. Birnbaum, and Timothy J. Johnson, Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director, Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, UV/Visible spectrum, References, Notes. Disclaimer, Copyright 2023 ChemSrc All Rights Reserved. Select a region with data to zoom. Agency for Toxic Substance and Disease Registration. Data, 1998, 43, 5, 770-775, https://doi.org/10.1021/je9701442 For the most part, studies in animals given trichlorobenzenes during pregnancy have not found adverse effects in the pups at birth or during the growing period. on behalf of the United States of America. It is a derivative of benzene with three chloride substituents. Sublimation Pressure Data for Organic Compounds., CHEMICAL NAME : Benzene, 1,2,4-trichloro- CAS REGISTRY NUMBER : 120-82-1 BEILSTEIN REFERENCE NO. Jones, A.H., Hydrophobic and volatile chemicals have proven to be difficult to dose in cell assays. 10. The acidity of chloro-substituted benzenes: A comparison of gas phase, ab initio, and kinetic data, 1,2,4-Trichlorobenzene, Last Updated Date : J. Chem. . T = temperature (K). It is useful as a high-temperature solvent, e.g. Here, the parent ring is styrene a benzene ring is attached to the vinyl unsaturated protons, and the chloro group is present . Promotional price valid on web orders only. Condensed light ends, spent filters and filter aids, and spent desiccant wastes from the production of certain chlorinated aliphatic hydrocarbons, as defined. How can trichlorobenzenes affect my health? 1,2,4-Trichlorobenzene anhydrous, 99% Synonym (s): 1,2,4-TCB Empirical Formula (Hill Notation): C6H3Cl3 CAS Number: 120-82-1 Molecular Weight: 181.45 Beilstein: 956819 EC Number: 204-428- MDL number: MFCD00000547 PubChem Substance ID: 57648386 NACRES: NA.21 Pricing and availability is not currently available. Use or mention of technologies or programs in this web site is not H315: Causes skin irritation. There is virtually no information regarding health effects of trichlorobenzenes in humans. Studies in animals indicate that oral administration of trichlorobenzenes for short or long periods produces mainly alterations in the liver and kidneys. . Chamblee, GA 30341-3717 Trichlorobenzenes tend to evaporate from water, but can also bind to suspended solids and sediment in water. Medium. Development of a partition-controlled dosing system for cell assays. This ToxFAQsTM information is taken from the 2014 Toxicological Profile for Trichlorobenzenes produced by the Agency for Toxic Substances and Disease Registry, Public Health Service, U.S. Department of Health and Human Services in Atlanta, GA. Huaxue Xuebao, 1987, 45, 1184-1187. Data compilation copyright PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine (e.g., INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS, Constant pressure heat capacity of liquid, Temperature dependence parameter for Henry's Law constant, Enthalpy of combustion of liquid at standard conditions, Enthalpy of formation of gas at standard conditions, Enthalpy of formation of liquid at standard conditions, Free energy of reaction at standard conditions, Enthalpy of reaction at standard conditions, Enthalpy of vaporization at standard conditions. Stull, Daniel R., Combustible. Your contract pricing may differ. The reaction is as follows: HeH + He + H +. Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References, Notes, Data compiled by: Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina, Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Notes, Yan, Gu, et al., 1987 Technology, Office of Data [all data], Stull, 1947 Trichlorobenzenes have primarily been used as solvents and chemical intermediates to produce other compounds. CAS 120-82-1, chemical formula CH-1,2,4- (Cl). H302: Harmful if swallowed. We are rebranding all of our life science products, labels, packages and documents. Your institution may already be a subscriber. PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-Trichlorobenzene Chemical group ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 2; . ; 1.) 1,2,4-Trichlorobenzene is a highly chlorinated aromatic solvent. Thermodynam., 1982, 14, 303-308. Russ. Notice: This spectrum may be better viewed with a Javascript Informational: This chemical may require us to obtain additional information for our regulatory and chemical compliance records. Explore, interact. ; Nibbering, N.M.M., Email: Contact CDC-INFO. J. Biologically Active Compounds | J., 2001, 7, 16, 3511-3516, https://doi.org/10.1002/1521-3765(20010817)7:16<3511::AID-CHEM3511>3.0.CO;2-U AC - William E. Acree, Jr., James S. Chickos The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Th This table shows how each list refers to the substance. Pioneering excellence with Steritest Symbio Pumps. Spieksma, Walter; Luijk, Ronald; Govers, Harrie A.J., by the U.S. Secretary of Commerce on behalf of the U.S.A. Eng. C6H3-1,2,4-(Cl)3. [all data], Platonov and Simulin, 1985 We do not know whether children would be more susceptible to the effects of trichlorobenzenes than adults. reaction search for this species. Measurements of (dV/dT)p, (dV/dP)T, and (dH/dT)p by flux calorimetry, Trichlorobenzene (TCB) may refer to any of three isomeric chlorinated derivatives of benzene with the molecular formula C6H3Cl3. InChI=1S/C6H3Cl3/c7-4-1-2-5(8)6(9)3-4/h1-3H, National Institute of Standards and Schlosser, M.; Marzi, E.; Cottet, F.; Buker, H.H. H315: Causes skin irritation. Chem. Follow the links above to find out more about the data Sears, G.W. Yan, H.; Gu, J.; An, X.; Hu, R., 2023 Merck KGaA, Darmstadt, Germany and/or its affiliates. such sites. 1,2,4-Trichlorobenzene, NIOSH: Pocket Guide to Chemical Hazards - MSDS/SDS Database Search | III. (1) The vapor pressure for 1,2,4-trichlorobenzene is 0.29 mm Hg at 25 C, and its log octanol/water partition [all data], van de Lande, 1932 1,2,4-Trichlorobenzene is an organochlorine compound, one of three isomers of trichlorobenzene. (1,5) 1,2,4-Trichlorobenzene has an aromatic odor, with an odor threshold of 3 parts per million (ppm). [all data], Sears and Hopke, 1949 View image of digitized You will need Adobe Reader to view some of the files on this page. B - John E. Bartmess Eng. : 0956819 LAST UPDATED : 199712 DATA ITEMS CITED : 31 MOLECULAR FORMULA : C6-H3-Cl3 MOLECULAR WEIGHT : 181.44 WISWESSER LINE NOTATION : GR BG DG HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : displays seen below. 2-Bromo-1,3,4-trichlorobenzene Understanding Solidification of Polythiophene Thin Films during Spin-Coating: Effects of Spin-Coating Time and Processing Additives. Copyright for NIST Standard Reference Data is governed by Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) Synonyms. Ruscic, B.; Klasinc, L.; Wolf, A.; Knop, J.V., https://en.wikipedia.org/w/index.php?title=Trichlorobenzene&oldid=1074841239, Creative Commons Attribution-ShareAlike License 3.0, This page was last edited on 2 March 2022, at 13:41. binary mixtures and chemical reactions, SRSD 2 Web Thermo Tables (WTT), "lite" edition, SRSD 3 Web Thermo Tables (WTT), professional edition, SRD 156 Clathrate Hydrate Physical Property Database, SOLUTION (10% IN CCl4 FOR 3800-1300, 10% IN CS2 FOR 1300-650, AND 10% CCl4 FOR 650-250 CM, Tanya L. Myers, Russell G. Tonkyn, Ashley M. Oeck, Tyler O. Danby, John S. Loring, Matthew S. Taubman, Stephen W. Sharpe, Jerome C. Birnbaum, and Timothy J. Johnson, liquid; Bruker Tensor 27 FTIR; 0.4821395 cm, NIST Mass Spectrometry Data Center, William E. Wallace, director, Modified by NIST for use in this application, Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina, https://doi.org/10.1016/0021-9673(94)80602-0, https://doi.org/10.1016/S0378-3812(99)00003-5, https://doi.org/10.1002/1521-3765(20010817)7:16<3511::AID-CHEM3511>3.0.CO;2-U. [4] There is no regulated occupational exposure limit for chemical exposure, but the National Institute for Occupational Safety and Health recommends no greater exposure than 5 ppm, over an 8-hour workday. Data Program, but require an annual fee to access. How can trichlorobenzenes affect children? This Website requires your browser to be JavaScript enabled. Benzene, 1,2,4-trichloro- Formula: C 6 H 3 Cl 3 Molecular weight: 181.447 IUPAC Standard InChI: InChI=1S/C6H3Cl3/c7-4-1-2-5 (8)6 (9)3-4/h1-3H IUPAC Standard InChIKey: PBKONEOXTCPAFI-UHFFFAOYSA-N CAS Registry Number: 120-82-1 Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file Standard enthalpies of formation and enthlpies of isomerization of trichlorobenzenes, 1,2,4-Trichlorobenzene is produced in large quantities and is used as a solvent to dissolve special materials such as oils, waxes, resins, greases, and rubber. 120-82-1. Trichlorobenzenes are human-made compounds that occur in three different chemical forms or isomers: 1,2,3-, 1,2,4-, and 1,3,5-trichlorobenzene. the The EPA has determined that exposure to 1,2,4-trichlorobenzene or 1,3,5-trichlorobenzene in drinking water at concentrations up to 0.1 and 0.6 milligrams per liter (mg/L), respectively, for 1 or 10 days is not expected to cause any adverse effects in a child. You will be subject to the destination website's privacy policy when you follow the link. NIST Standard Reference Trichlorobenzenes are volatile and preferentially enter the air when released to the environment. CAS 120-82-1, chemical formula CH-1,2,4-(Cl). P264: Wash skin thoroughly after handling. Pays-Bas, 1932, 51, 98-113. They help us to know which pages are the most and least popular and see how visitors move around the site. Compound E is 4-Bromo 1-chloro 2-methyl benzene. Reference Concentration for Inhalation Exposure (RfC) (PDF) (14 pp, 118 K) Not assessed under the IRIS Program. ; Coefficents calculated by NIST from author's data. Reference Dose for Oral Exposure (RfD) (PDF) (14 pp, 118 K) . - 298. spectrum (can be printed in landscape orientation). for GPC of polyolefines such as PE or PP which are otherwise insoluble. J. Chem. United States Environmental Protection Agency. Acta, 1986, 105, 101-110. . These cookies may also be used for advertising purposes by these third parties. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 Primary and secondary antibodies, blockers and custom services. Follow the links above to find out more about the data Tunnel Dmagntiseurs Plans d'expansion futurs du march, demande par rgions jusqu'en 2030. Rohc, Vladislav; Ruzicka, Vlastimil; Ruzicka, Kvetoslav; Aim, Karel, Here, we systematically characterize th Chem. Molecular Weight 181.45. Cookies used to enable you to share pages and content that you find interesting on CDC.gov through third party social networking and other websites. Total Toxic Organics (TTO) Effluent Guidelines Part 413.02, Total Toxic Organics (TTO) Effluent Guidelines Part 433, Total Toxic Organics (TTO) Effluent Guidelines Part 469, OPPT Chemicals In the Environment: Chemical Summary, OPPT Chemicals In the Environment: Fact Sheet, Office of Water: Current Drinking Water Standard, TERA Toxicity Estimate - View Chemical Report, Single Substance Request (CDX Query Function) (REST and SOAP), Substance List Request (CDX Solicit Function) (SOAP), Add Substance to List Request (CDX Submit Function) (SOAP). Res. Toggle navigation. 1,2,3-Trichlorobenzene and 1,3,5-trichlorobenzene are colorless solids, but 1,2,4-trichlorobenzene is a colorless oil. ), 1985, 59, 179-181. H410: Very toxic to aquatic life with long lasting effects. ; Hopke, E.R., Jondorf, W.R.; Williams, R.T., [all data], Wilhelm, Inglese, et al., 1982 It is mainly used as intermediate in dyes, pesticides and also as a lubricant. Moreover, the free concentration Get all suppliers and price by the below link: Home | HTMO1WHCH=bJT;q&a2v=|W~^b6Lmr"{OL{yP7?Nk.TTA(#` FxS*Ah,YjjKSTF9x:q0ffvn 0htoh D"od,,76=:(x K. See also. Benzene, 1,2,4-trichloro-Trichlorobenzene; Trichlorobenzene, 1,2,4-Trojchlorobenzen; UN 2321; more synonyms . Chemical Structure for 1,2,4-Trichlorobenzene. To view more metadata about the specific Synonym, click on the Synonym. Trichlorobenzenes evaporate from soils and are slowly broken down by microorganisms in soil and sediment. Catalog number: 157900025. [all data], Ruscic, Klasinc, et al., 1981 1 x 10 -2. uses its best efforts to deliver a high quality copy of the If you have questions or concerns, please contact your community or state health or environmental quality department or: For more information, contact: ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein Colorless liquid or crystalline solid (below 63F) with an aromatic odor. Create the perfect solution - match and clear hexagones. reaction search pages in place of the enumerated reaction The following list includes links related to the selected substance. [all data], Wilhelm, Lainez, et al., 1986 This substance exists as a Related Substance of the following substances. SRD 103a Thermo Data Engine (TDE) for pure compounds. Office of Innovation and Analytics, Toxicology Section Biochem. Institute of Standards and Technology, nor is it intended to imply A-006. Fluid Phase Equilibria, 1999, 157, 1, 121-142, https://doi.org/10.1016/S0378-3812(99)00003-5 9-9BNKN!%Si)gNAGj!{pp{Pa9#b0RFH1r8(Byy4(L4iPhAAOJ= * T~_O)~?/S~_oF\B[Nn{(}fPyqMKo D4' . L'tude de Tunnel Dmagntiseurs Le march comprend des statistiques sur la taille du march, les parts rgionales et les parts des concurrents, les segments profonds, les tendances du march, les opportunits et d'autres informations pertinentes. It is also the main product from the dehydrochlorination of hexachlorocyclohexane.[3]. The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. Price (EUR) Price: 98,60. About Us | Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes, kH(T) = kH exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K))) Soc., 1952, 74, 3890-1. Last Updated: 05/01/1992. See EPAs PDF page to learn more. NIST subscription sites provide data under the Buying Leads | P = vapor pressure (bar) #=0!w}S&!T7U/9s$5U]O~K%~ed>7ueY?*us6/Wn]/LfSG{q&^{Wz;Ec' SUvE9d"Mxx*?~:YfDK(@+hwh'3hbc^.P)d!9(@ !pqp888 j"Si)rZr Recommended vapour and sublimation pressures and related thermal data for chlorobenzenes, The . Chim. [all data], Jones, 1960 Watch, learn and engage with us. 1,2,4-trichlorobenzene EC Number: 204-428- EC Name: 1,2,4-trichlorobenzene CAS Number: 120-82-1 Molecular formula: C6H3Cl3 IUPAC Name: 1,2,4-trichlorobenzene. Synonyms: 1,2,4-Trichlorobenzene. and Informatics, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data), Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein. Cosolvents are often needed to dissolve these chemicals in cell culture medium. If required, we will contact you for this information once your order is placed. with the development of data collections included in What is claimed is: 1. that these items are necessarily the best available for the purpose. in these sites and their terms of usage. HeH + contains all paired electrons. Formula. HeH + has bond order 1.. Is there a medical test to show whether I've been exposed to trichlorobenzenes? Physical Properties. Chem. Your institution may already be a subscriber. Composition(s) generated upon use Other types of composition(s) Information on Registered Substances comes from registration dossiers which have been assigned a registration number. What Generation is Your Sterility Testing Pump? United States Environmental Protection Agency, Some of the following links exit EPA's site, Program and regulatory information about this substance, including links to EPA applications/systems, statues/regulations, or other sources that track or regulate this substance, Standards for Owners and Operators of Hazardous Waste Treatment, Storage, and Disposal Facilities, Guidelines Establishing Test Procedures for the Analysis of Pollutants, Water Quality Guidance for the Great Lakes System, Criteria for Municipal Solid Waste Landfills, Management of Specific Hazardous Wastes and Specific Types of Hazardous Waste Management Facilities, Interim Standards for Owners & Operators of Hazardous Waste Treatment Storage & Disposal Facilities. [all data], Rohc, Ruzicka, et al., 1999 The quantity field is empty. Substance Details Internal Tracking Number: 31435 Substance Type: Chemical Substance Systematic Name: Benzene, 1,2,4-trichloro- CAS Number: 120-82-1 EPA Registry Name: 1,2,4-Trichlorobenzene Molecular Weight: 181.45 Molecular Formula: C6H3Cl3 Additional Metadata However, NIST makes no warranties to that effect, and NIST 12/14/2020, Occupational Safety & Health Administration, Occupational Safety and Health Administration, Outreach Training Program (10- and 30-hour Cards), OSHA Training Institute Education Centers, Severe Storm and Flood Recovery Assistance. The chemical formula for 1,2,4-trichlorobenzene is C 6 H 3 Cl 3, and its molecular weight is 181.46 g/mol. 1,2,4-Trichlorobenzene Valid: 09/29/1987: RCRA Appendix VII 1,2,4-Trichlorobenzene Valid: 05/19/1980: EG Part 413 1,2,4-Trichlorobenzene Valid: 07/31/2018: Management of Specific Hazardous Wastes and Specific Types of Hazardous Waste Management Facilities 1,2,4-Trichlorobenzene Valid It is not known whether trichlorobenzenes could affect reproduction in humans. 6.1C Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects, harmful, irritant, dangerous for the environment, UN 2321 , 6.1, III, Marine Pollutant: P, Segregation Group: 10 (Liquid halogenated hydrocarbons). Determination of the liquid vapour pressure of low-volatility compounds from the Kovts retention index, The product quantity has been adjusted. shall not be liable for any damage that may result from Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes. [all data], Jondorf and Williams, 1958 Synthesis Reference(s): Journal of the American Chemical Society, 74, p. 3890, 1952 DOI: 10.1021/ja01135a052: Physical Properties for CAS 120-82-1: J. Phys. kH = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar)) The lower energy states of HeH + is reached when product formed are He + H +.. 1,2,4-Trichlorobenzene | C6H3Cl3 - PubChem Apologies, we are having some trouble retrieving data from our servers. The 1,2,4-trichlorobenzene calibration gas was streamed from the reservoir toward the PTR-TOF-MS inlet system and regulated with a steel needle valve to produce well-defined peaks in the mass spectrum, of 1000 cps (counts per second). Huaxue Xuebao, 1987, 45, 1184. Recl. Please enter a quantity of 1 or more to add items to your cart. Toxicol. intended to imply recommendation or endorsement by the National Merck KGaA, Darmstadt, Germany, 2014. J., 1958, 69, 181. Exit. NIST subscription sites provide data under the Wilhelm, E.; Lainez, A.; Roux, A.H.; Grolier, J.-P.E., Organic residuals, excluding spent carbon adsorbent, from the spent chlorine gas and hydrochloric acid recovery processes associated with the production of alpha- (or methyl-) chlorinated toluenes, ring-chlorinated toluenes, benzoyl chlorides, and compounds with mixtures of these functional groups. Molar excess volumes and excess heat capacities of (1,2,4-trichlorobenzene + an alkane), Not assessed under the IRIS Program. Photoelectron spectra of and Ab initio calculations on chlorobenzenes. 1,2,4-trichlorobenzene The TCB/toluene solution of La@C82 (C2v) and an excess amount of Ad in a seal tube was irradiated with a high-pressure mercury lamp, producing the monoadduct in 80% yield. 1,2,3-Trichlorobenzene and 1,3,5-trichlorobenzene are colorless solids, but 1,2,4-trichlorobenzene is a colorless oil. 1,2,3-Trichlorobenzene and 1,3,5-trichlorobenzene are colorless solids, while 1,2,4 trichlorobenzene is a colorless liquid. Training programs and seminars designed for you. endstream endobj 26 0 obj <>stream Selling Leads | P264: Wash skin thoroughly after handling. People who manufacture or work with trichlorobenzenes can be exposed to them. Even though the forms have the same molecular weight and molecular formulae, they are structurally different by the positions of the chlorine atoms attached to the benzene ring. J. Chem. : Washington, D. C., 1955. The preparation method of any one of Claims 1 to 9, wherein, the first solvent is selected from one or a mixture of two or more of 1,2,4-trichlorobenzene, o-dichlorobenzene, chlorobenzene, anisole, toluene, nitrobenzene, isopropyl alcohol, This fact sheet answers the most frequently asked health questions (FAQs) about trichlorobenzenes. All Rights Reserved. 1,2,4-Trichlorobenzene for synthesis. CAS 120-82-1. Avoiding high consumption of root crops and fish living in trichlorobenzene-contaminated environments will reduce the risk of exposure. following TRC products: Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes. [all data], Spieksma, Luijk, et al., 1994 The EPA has stated that 1,2,4-trichlorobenzene is not classifiable as to human carcinogenicity. It is a derivative of benzene, consisting of two adjacent chlorine atoms.. Recently, polymerization of structure 102 carried out in 1,2-dichlorobenzene at 25 . Anion assigned based on ab initio calculations. Am. Some documentation and label information may refer to the legacy brand. QSPR modeling of octanol/water partition coefficient for vitamins by optimal descriptors calculated with SMILES. NIST Standard Reference A new class of spectrophotometers for water analysis. Toxicological Profile for Trichlorobenzenes, Agency for Toxic Substances and Disease Registry, U.S. Department of Health & Human Services. Standard Reference Data Act. CDC is not responsible for Section 508 compliance (accessibility) on other federal or private website. However, based on results from studies in animals, it is reasonable to predict that humans exposed to high amounts of trichlorobenzenes may develop liver problems. Thank you for taking the time to confirm your preferences. Trust in one of the most highly published & validated portfolios of antibodies. Has the federal government made recommendations to protect human health? NOAEL : 1.48 x 10 1. mg/kg-day. (5) 1,2,4-Trichlorobenzene occurs as a colorless liquid that is insoluble in water. Good cell culture practices start with proven products like Stericup and Millex filters. form is van de Lande, L.M.F., T = 297 to 454 K. Value is unsmoothed experimental datum. SRD 103b Thermo Data Engine (TDE) for pure compounds, Benzene, 1,2,4-trichloro- Formula: C 6 H 3 Cl 3 Molecular weight: 181.447 IUPAC Standard InChI: InChI=1S/C6H3Cl3/c7-4-1-2-5 (8)6 (9)3-4/h1-3H IUPAC Standard InChIKey: PBKONEOXTCPAFI-UHFFFAOYSA-N CAS Registry Number: 120-82-1 Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file The Action of Sodium Methylate on SOme Derivatives of m-Dichlorobenzene, InChI=1/C6H3Cl3/c7-4-1-2-5(8)6(9)3-4/h1-3H<, Except where otherwise noted, data are given for materials in their, National Institute for Occupational Safety and Health, Ullmann's Encyclopedia of Industrial Chemistry, CDC - NIOSH Pocket Guide to Chemical Hazards, https://en.wikipedia.org/w/index.php?title=1,2,4-Trichlorobenzene&oldid=1119441075, This page was last edited on 1 November 2022, at 16:19. Sears, G.W from water, but can also bind to suspended solids and.... 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